1-Methoxy-2-propanol
- Propylene glycol, monomethyl ether
- 1-Methoxy-propane-2-ol
- 1-Methoxy-2-hydroxypropane
1-Methoxy-2-propanol | |
| |
| Formula | C4H10O2 |
| Structure | |
| Description | Clear colorless liquid with ether-like odor, lachrymator, hygroscopic. |
| Uses | Chiefly used in manufacture of lacquers & paints. |
| Registry Numbers and Inventories. | |
| CAS | 107-98-2 |
| EC (EINECS/ELINCS) | 203-539-1 |
| EC Index Number | 603-064-00-3 |
| EC Class | Flammable |
| EC Risk Phrase | R 10 |
| EC Safety Phrase | S 24 |
| RTECS | UB7700000 |
| RTECS class | Reproductive Effector; Human Data; Primary Irritant |
| UN (DOT) | 3092 |
| Beilstein/Gmelin | 1731270 |
| Beilstein Reference | 3-01-00-02146 |
| Swiss Giftliste 1 | G-2805 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C4H10O2 |
| Formula mass | 90.12 |
| Melting point, °C | -97 |
| Boiling point, °C | 119.6 |
| Vapor pressure, mmHg | 12 |
| Vapor density (air=1) | > 1 |
| Saturation Concentration | About 1.5% (15000 ppm) at 25 C (calculated) |
| Evaporization number | About 0.7 (butyl acetate = 1) |
| Critical temperature | 307 |
| Critical pressure | 40.59 |
| Density | 0.9335 g/cm3 (15 C) |
| Solubility in water | Miscible |
| Viscosity | 1.67 cp (25 C) |
| Surface tension | 27.7 g/s2 |
| Refractive index | 1.4034 (20 C) |
| Heat of vaporization | 32.6 kJ/mol |
| Heat of combustion | -2324 kJ/mol |
| Hazards and Protection. | |
| Storage | Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep containers tightly closed. |
| WHMIS | B2 D2B |
| Handling | Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. |
| Respirators | Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. A vapor suppressing foam may be used to reduce vapors. |
| Disposal code | 1 |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Strong oxidizing agents. |
| Decomposition | Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | 31 | |||
| Autoignition, °C | 287 | |||
| Upper exp. limit, % | 13.8 | |||
| Lower exp. limit, % | 1.6 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. | |||
| Fire potential | FLAMMABLE. | |||
| Hazards | Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. | |||
| Combustion products | Fire may produce irritating, corrosive and/or toxic gases. | |||
| NFPA | Health | 0 | ||
| Flammability | 3 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | TLV: 100 ppm; 369 mg/m3 (as TWA); 150 ppm; 553 mg/m3 (STEL) (ACGIH 1997). MAK: 100 ppm; 375 mg/m3; (1996) NIOSH REL: TWA 100 ppm (360 mg/m3) ST 150 ppm (540 mg/m3) |
| Poison_Class | - |
| Exposure effects | Repeated or prolonged exposure may cause CNS stimulation. |
| Ingestion | May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. |
| Inhalation | Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. |
| Skin | May cause skin irritation. Prolonged and/or frequent contact may cause drying, cracking or folliculitis. |
| Eyes | May cause eye irritation. |
First aid |
|
| Ingestion | If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. |
| Skin | Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| UN number | 3092 | |
| Response guide | 129 | |
| Hazard class | 3 | |
| Packing Group | III | |
| USCG CHRIS Code | PME | |
| USCG Compatatibility Group | 40 Glycol ethers | |
| HS Code | 2909 49 19 | |
| Std. Transport # | 4909309 | |
| IMO Chemical Code | 18 | |
| IMO Pollution Category | D | |