Allyl glycidyl ether
- 1-(Allyloxy)-2,3-epoxypropane
- Allyl 2,3-epoxypropyl ether
- ((2-propenyloxy)methyl)oxirane
Allyl glycidyl ether | |
| |
| Formula | C6H10O2 |
| Structure | |
| Description | Colorless liquid, characteristic, sweet odor. |
| Uses | Stabilizer of chlorinated compounds, vinyl resins, rubber, resin intermediate. |
| Registry Numbers and Inventories. | |
| CAS | 106-92-3 |
| EC (EINECS/ELINCS) | 203-442-4 |
| EC Index Number | 603-038-00-1 |
| EC Class | Flammable; Carcinogenic Category 3; Mutagenic Category 3; Toxic for reproduction Category 3; Harmful; Irritant; Sensitising; Dangerous for the Environment |
| EC Risk Phrase | R 10 20/22 40 41 43 52/53 62 68 |
| EC Safety Phrase | S 24/25 26 36/37/39 61 |
| RTECS | RR0875000 |
| RTECS class | Tumorigen; Mutagen; Primary Irritant |
| UN (DOT) | 2219 |
| Beilstein/Gmelin | 105871 |
| Beilstein Reference | 5-17-03-00012 |
| Swiss Giftliste 1 | G-1064 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C6H10O2 |
| Formula mass | 114.15 |
| Melting point, °C | -100 |
| Boiling point, °C | 154 |
| Vapor pressure, mmHg | 5 |
| Vapor density (air=1) | 3.94 |
| Saturation Concentration | 6200 ppm (0.62%) at 25 C (1) |
| Critical temperature | 320 |
| Critical pressure | 36.4 |
| Density | 0.9798 g/cm3 |
| Solubility in water | 141 g/L |
| Refractive index | 1.4349 (20 C) |
| Partition coefficient, pKow | 0.36 |
| Hazards and Protection. | |
| Storage | Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. |
| Handling | Wash thoroughly after handling. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Use and store under nitrogen. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. |
| Small spills/leaks | Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Use a spark-proof tool. Provide ventilation. |
| Disposal code | 1 |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Oxidizing agents, acids, bases. |
| Decomposition | Carbon monoxide, carbon dioxide, acrid smoke and fumes. |
| Fire. | ||||
| Flash Point,°C | 48 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. | |||
| Fire potential | HIGHLY FLAMMABLE. | |||
| Hazards | Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | |||
| Combustion products | Fire may produce irritating, corrosive and/or toxic gases. | |||
| NFPA | Health | 2 | ||
| Flammability | 2 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | OSHA PEL: C 10 ppm (45 mg/m3) NIOSH REL: TWA 5 ppm (22 mg/m3) ST 10 ppm (44 mg/m3) skin NIOSH IDLH: 50 ppm |
| Poison_Class | 3 |
| Exposure effects | Repeated exposure may cause sensitization dermatitis. |
| Ingestion | May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May cause central nervous system depression. |
| Inhalation | Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation at high concentrations may cause CNS depression and asphixiation. Harmful if inhaled. |
| Skin | Causes severe skin irritation. May be harmful if absorbed through the skin. May cause cyanosis of the extremities. May cause sensitization by skin contact. |
| Eyes | Causes severe eye irritation. May cause reversible inflammation and corneal injury with opacity. Vapors may also cause corneal opacity. |
First aid |
|
| Ingestion | Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. |
| Skin | Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| UN number | 2219 | |
| Response guide | 129 | |
| Hazard class | 3 | |
| Packing Group | III | |
| USCG CHRIS Code | AGE | |
| HS Code | 2910 90 00 | |
| Std. Transport # | 4912078 | |