Diethyl phthalate
- Phthalic acid, diethyl ester
- 1,2-Benzenedicarboxylic acid, diethyl ester
- Ethyl phthalate
- DEP
Diethyl phthalate | |
| |
| Formula | C12H14O4 |
| Structure | |
| Description | Water-white to colorless, odorless, oily liquid. |
| Uses | In manufacture celluloid, solvent for cellulose acetate in manufacture varnishes & dopes, fixative for perfumes, denaturing alcohol. |
| Registry Numbers and Inventories. | |
| CAS | 84-66-2 |
| EC (EINECS/ELINCS) | 201-550-6 |
| EC Risk Phrase | R 36/38 |
| EC Safety Phrase | S 26 36 |
| RTECS | TI1050000 |
| RTECS class | Tumorigen; Mutagen; Reproductive Effector; Human Data; Primary Irritant |
| Merck | 12,7527 |
| Beilstein/Gmelin | 1912500 |
| Beilstein Reference | 4-09-00-03172 |
| RCRA | U088 |
| EPA OPP | 128947 |
| Swiss Giftliste 1 | G-3186 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C12H14O4 |
| Formula mass | 222.24 |
| Melting point, °C | -3 |
| Boiling point, °C | 298 |
| Vapor pressure, mmHg | 0.00081 (25 C) |
| Vapor density (air=1) | 7.6 |
| Saturation Concentration | 2.17 ppm (.0002%) at 25 C (calculated) |
| Density | 1.13592 g/cm3 (0 C) |
| Solubility in water | 1 g/L |
| Viscosity | 2.15 cp (86 C) |
| Surface tension | 37.5 g/s2 (20 C) |
| Refractive index | 1.5000 (21C) |
| Partition coefficient, pKow | 2.47 |
| Heat of vaporization | 63.30 kJ/mol |
| Heat of combustion | -5582 kJ/mol |
| Hazards and Protection. | |
| Storage | Keep away from heat and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. |
| Handling | Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. |
| Disposal code | 1 |
| Stability | Stable under normal shipping and handling conditions. |
| Incompatibilities | Strong acids such as nitric acid, strong oxidizing agents, and permanganates. |
| Decomposition | Carbon monoxide, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | 156 | |||
| Autoignition, °C | 430 | |||
| Upper exp. limit, % | 5.3 | |||
| Lower exp. limit, % | 0.7 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. | |||
| Fire potential | Slightly flammable. Requires preheating. | |||
| Combustion products | Irritating vapors of unburned chemical may form in fire. | |||
| NFPA | Health | 1 | ||
| Flammability | 1 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | TLV (as TWA): 10 ppm; 5 mg/m3 (ACGIH 1992-1993). NIOSH REL: TWA 5 mg/m3 |
| Poison_Class | 4 |
| Exposure effects | May cause fetal effects. |
| Ingestion | Causes gastrointestinal irritation with nausea, vomiting and diarrhea. |
| Inhalation | Causes respiratory tract irritation. May cause narcotic effects in high concentration. |
| Skin | Causes skin irritation. |
| Eyes | Contact produces irritation, tearing, and burning pain. |
First aid |
|
| Ingestion | Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. |
| Inhalation | Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. |
| Skin | Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
| Transport. | ||
| USCG CHRIS Code | DPH | |
| USCG Compatatibility Group | 34 Esters | |
| HS Code | 2917 34 00 | |
| Std. Transport # | 4962112 | |
| IMO Chemical Code | 17 | |
| IMO Pollution Category | C | |
| IMO Hazard code | P | |