Diethylaminoethanol
- Diethylethanolamine
- 2-Diethylamionethanol
- 2-Hydroxytriethylamine
Diethylaminoethanol | |
| |
| Formula | (C2H5)2NCH2CH2OH |
| Structure | |
| Description | Clear, colorless liquid, nauseating, unpleasant, weak, ammonia-like odor, hygroscopic. |
| Uses | Manufacture of emulsifying agents and special soaps. |
| Registry Numbers and Inventories. | |
| CAS | 100-37-8 |
| EC (EINECS/ELINCS) | 202-845-2 |
| EC Index Number | 603-048-00-6 |
| EC Class | Flammable; Harmful; Corrosive |
| EC Risk Phrase | R 10 20/21/22 34 |
| EC Safety Phrase | S 25 26 36/37/39 45 |
| RTECS | KK5075000 |
| RTECS class | Human Data; Primary Irritant |
| UN (DOT) | 2686 |
| Merck | 13,3139 |
| Beilstein/Gmelin | 741863 |
| Beilstein Reference | 4-04-00-01471 |
| Swiss Giftliste 1 | G-1873 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C6H15NO |
| Formula mass | 117.19 |
| Melting point, °C | -70 |
| Boiling point, °C | 162 |
| Vapor pressure, mmHg | 21 (25 C) |
| Vapor density (air=1) | 4.03 |
| Saturation Concentration | About 0.18% (1800 ppm) at 25 C (calculated) |
| Evaporization number | 0.17 (butyl acetate = 1) |
| Critical temperature | 343 |
| Critical pressure | 26.15 |
| Density | 0.8921 g/cm3 (20 C) |
| Solubility in water | Miscible |
| Viscosity | 4.022 cp (25 C) |
| Surface tension | 29.2 g/s2 at 20 C |
| Refractive index | 1.4389 (20 C) |
| Dielectric constant | 9.1 (20 C) |
| pKa/pKb | 4.13 (pKb) |
| Heat of vaporization | 45.0 kJ/mol |
| Hazards and Protection. | |
| Storage | Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture. |
| WHMIS | B3 D1B E |
| Handling | Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. |
| Disposal code | 1 |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Acids, copper, copper alloys, zinc, galvanized iron, nitrites, strong oxidizing agents, metals, acid anhydrides. |
| Decomposition | Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen. |
| Fire. | ||||
| Flash Point,°C | 51.5 | |||
| Autoignition, °C | 270 | |||
| Upper exp. limit, % | 28 | |||
| Lower exp. limit, % | 1.8 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out. | |||
| Fire potential | Flammable; moderate fire hazard | |||
| Hazards | Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |||
| Combustion products | Toxic and irritating gases may be generated. | |||
| NFPA | Health | 1 | ||
| Flammability | 2 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | OSHA PEL: TWA 10 ppm (50 mg/m3) skin NIOSH REL: TWA 10 ppm (50 mg/m3) skin NIOSH IDLH: 100 ppm |
| Poison_Class | 4 |
| Exposure effects | |
| Ingestion | Harmful if swallowed. Causes gastrointestinal tract burns. |
| Inhalation | Harmful if inhaled. Causes chemical burns to the respiratory tract. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. |
| Skin | May cause severe skin irritation. May be harmful if absorbed through the skin. |
| Eyes | May cause eye irritation. May cause eye injury. |
First aid |
|
| Ingestion | If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. |
| Skin | Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Eyes | Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| UN number | 2686 | |
| Response guide | 132 | |
| Hazard class | 8 | |
| Packing Group | II | |
| USCG CHRIS Code | DAE | |
| USCG Compatatibility Group | 8 Alkanolamines | |
| HS Code | 2922 19 80 | |
| Std. Transport # | 4912086 4930002 | |
| IMO Pollution Category | C | |
| IMO Hazard code | S/P | |