Dimethyl phthalate
- 1,2-Benzenedicarboxylic acid, dimethyl ester
- 1,2-Dimethyl phthalate
- Phthalic acid dimethyl ester
Dimethyl phthalate | |
| |
| Formula | C10H10O4 |
| Structure | |
| Description | Colorless, oily liquid, pale yellow crystals, slight aromatic odor. |
| Uses | Insect repellent. |
| Registry Numbers and Inventories. | |
| CAS | 131-11-3 |
| EC (EINECS/ELINCS) | 205-011-6 |
| EC Risk Phrase | R 40 |
| EC Safety Phrase | S 36/37 |
| RTECS | TI1575000 |
| RTECS class | Agricultural Chemical and Pesticide; Mutagen; Reproductive Effector; Primary Irritant |
| UN (DOT) | 9188 |
| Merck | 13,3281 |
| Beilstein/Gmelin | 1911460 |
| Beilstein Reference | 4-09-00-03170 |
| RCRA | U102 |
| EPA OPP | 28002 |
| Swiss Giftliste 1 | G-1563 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C10H10O4 |
| Formula mass | 194.19 |
| Melting point, °C | 6 |
| Boiling point, °C | 283.7 |
| Vapor pressure, mmHg | 0.029 (25 C) |
| Vapor density (air=1) | 6.69 |
| Saturation Concentration | <13 ppm at 20 C (calculated) |
| Evaporization number | Almost zero |
| Critical temperature | 24.4 |
| Density | 1.192 g/cm3 (20 C) |
| Solubility in water | 4.3 g/L |
| Viscosity | 13.92 cp (25 C) |
| Surface tension | 41.85 g/s2 (20 C) |
| Refractive index | 1.5168 (20 C) |
| Partition coefficient, pKow | 1.60 |
| Heat of vaporization | 80.8 kJ/mol |
| Heat of combustion | -4680 kJ/mol |
| Hazards and Protection. | |
| Storage | Store in a cool, dry place. Store in a tightly closed container. |
| Handling | Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. |
| Disposal code | 1 |
| Stability | Stable in air but slowly affected by light. |
| Incompatibilities | Oxidizing agents, acids, bases, and nitrates. |
| Decomposition | Carbon monoxide, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | 150 | |||
| Autoignition, °C | 460 | |||
| Upper exp. limit, % | 5.8 | |||
| Lower exp. limit, % | 0.9 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. | |||
| Fire potential | This chemical is combustible. | |||
| Hazards | Containers may explode when heated. | |||
| Combustion products | Fire may produce irritating, corrosive and/or toxic gases. | |||
| NFPA | Health | 1 | ||
| Flammability | 1 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | TLV (as TWA): ppm; 5 mg/m3 (ACGIH 1994-1995). OSHA PEL: TWA 5 mg/m3 NIOSH REL: TWA 5 mg/m3 NIOSH IDLH: 2000 mg/m3 |
| Poison_Class | 4 |
| Exposure effects | Abnormally low blood pressure after ingestion of deet may occur. Acute exposure - neurologic: Dizziness occurred in a human exposure to 10 g of dbp. Polyneuritis was reported in one soviet study. There have been several animal and laboratory tests done on the possible teratogenic effect of DBP. The results have been mixed. Studies done on Salmonella cultures have shown mildly positive mutagenic responses. DBP appears to affect females more than males, at least in the rodent studies performed. |
| Ingestion | Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression. |
| Inhalation | Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. |
| Skin | May cause skin irritation. |
| Eyes | Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. |
First aid |
|
| Ingestion | If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. |
| Skin | Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| UN number | 9188 | |
| Response guide | 171 | |
| Hazard class | 9 | |
| USCG CHRIS Code | DTL | |
| USCG Compatatibility Group | 34 Esters | |
| HS Code | 2917 34 00 | |
| Std. Transport # | 4962114 | |
| IMO Chemical Code | 17 | |
| IMO Pollution Category | C | |
| IMO Hazard code | P | |