Ethyl bromide
- Bromoethane
Ethyl bromide | |
| |
| Formula | CH3CH2Br |
| Structure | |
| Description | Colorless liquid with ether-like odor. Becomes yellow on exposure to air and light, gas above 38 deg c. |
| Uses | Ethylating agent in organic synthesis, refrigerant. |
| Registry Numbers and Inventories. | |
| CAS | 74-96-4 |
| EC (EINECS/ELINCS) | 200-825-8 |
| EC Index Number | 602-055-00-1 |
| EC Class | Highly flammable; Carcinogenic Category 3; Harmful |
| EC Risk Phrase | R 20/22 40 |
| EC Safety Phrase | S 36/37 |
| RTECS | KH6475000 |
| RTECS class | Tumorigen; Mutagen |
| UN (DOT) | 1891 |
| Merck | 13,3807 |
| Beilstein/Gmelin | 1209224 |
| Beilstein Reference | 4-01-00-00150 |
| Swiss Giftliste 1 | G-1166 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Properties. | |
| Formula | C2H5Br |
| Formula mass | 108.97 |
| Melting point, °C | -118 |
| Boiling point, °C | 38.4 |
| Vapor pressure, mmHg | 467 (25 C) |
| Vapor density (air=1) | 3.76 |
| Saturation Concentration | 494000 ppm (49.4%) at 20 C (calculated) |
| Critical temperature | 231 |
| Critical pressure | 61.50 |
| Density | 1.460 g/cm3 (20 C) |
| Solubility in water | 9 g/L |
| Viscosity | 0.40 cp (20 C) |
| Surface tension | 24.15 g/s2 @ 20 C |
| Refractive index | 1.4242 (20 C) |
| Partition coefficient, pKow | 1.61 |
| Heat of fusion | 5.86 kJ/mol |
| Heat of vaporization | 27.6 kJ/mol |
| Heat of combustion | -1380 kJ/mol |
| Hazards and Protection. | |
| Storage | Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep away from water. |
| Handling | Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal. |
| Disposal code | 2 |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Strong bases, strong oxidizers, magnesium, and water. |
| Decomposition | Carbon monoxide, carbon dioxide, hydrogen bromide. |
| Fire. | ||||
| Flash Point,°C | -20 | |||
| Autoignition, °C | 510 | |||
| Upper exp. limit, % | 11.3 | |||
| Lower exp. limit, % | 6.7 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use carbon dioxide or dry chemical. DO NOT USE WATER! | |||
| Fire potential | HIGHLY FLAMMABLE. | |||
| Hazards | Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | |||
| Combustion products | Readily decomposes into volatile toxic products. | |||
| NFPA | Health | 3 | ||
| Flammability | 3 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | NIOSH REL: See Appendix D OSHA PEL: TWA 200 ppm (890 mg/m3) IDLH 2000 ppm |
| Carcinogin | G-A3, CP65 |
| Poison_Class | 4 |
| Exposure effects | Prolonged or repeated skin contact may cause irritation. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause cancer in humans. |
| Ingestion | May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause respiratory failure. May cause systemic toxic effects on the heart, liver, and kidneys. |
| Inhalation | Causes respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause effects similar to those described for ingestion. Causes narcotic effects including headache, dizziness, weakness, unconsciousness, and possible death. |
| Skin | Causes skin irritation. Exposure may cause irritation characterized by redness, dryness, and inflammation. |
| Eyes | Causes eye irritation. |
First aid |
|
| Ingestion | If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. |
| Skin | Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| UN number | 1891 | |
| Response guide | 131 | |
| Hazard class | 6.1 | |
| Packing Group | II | |
| HS Code | 2903 30 36 | |
| Std. Transport # | 4921573 | |