Graphite

  • Mineral carbon
  • Black lead
  • Plumbago
Formula C
Structure
Description Steel gray to black, greasy feeling, odorless solid.
Uses For lead pencils, refractory crucibles, stove polish.

Registry Numbers and Inventories.
CAS 7782-42-5
EC (EINECS/ELINCS) 231-955-3
RTECS MD9659600
RTECS class Other
UN (DOT) 1361
Merck 12,4560
Beilstein/Gmelin 7851 (G)
Swiss Giftliste 1 G-8422
Canada DSL/NDSL DSL
US TSCA Listed
Austrailia AICS Listed
New Zealand Listed
Korea ECL Listed

Properties.
Formula C
Formula mass 12.01
Melting point, °C 3827
Vapor pressure, mmHg 380 (2220 C)
Density 2.09-2.23 g/cm3 (20 C)
Solubility in water Insoluble
Thermal expansion 1.7E-6/K (20 C)
Heat of fusion 104.6 kJ/mol

Hazards and Protection.
Storage Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection Protective gloves. Safety goggles -- in combination with breathing protection if a powder.
Respirators Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.
Stability No data.
Incompatibilities The substance is a strong reducing agent and reacts with oxidizers.

Fire.
Autoignition, °C 449
Fire fighting Small Fires: Dry chemical, carbon dioxide, sand, earth, water spray or regular foam. Large Fires: Water spray, fog or regular foam.
Fire potential Flammable/combustible material. May be ignited by friction, heat, sparks or flames.
Combustion products Fire may produce irritating and/or toxic gases.
NFPA Health 1
  Flammability 0  
  Reactivity 0  

Health.
Exposure limit(s) TLV: ppm; 2.0 mg/m3 as respirable dust (ACGIH 1996-1997). OSHA PEL: TWA 15 mg/m3 NIOSH REL: TWA 2.5 mg/m3 (resp) NIOSH IDLH: 1250 mg/m3
Poison_Class -
Exposure effects The toxological properties of this substance have not been fully investigated.
   Inhalation Cough. Long term/repeated exposure can affect lungs, resuling in graphite pneumoconiosis.
   Skin Roughness.
   Eyes See Skin.

First aid
 
   Ingestion Seek medical assistance.
   Inhalation Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes. Wash skin with soap and water.
   Eyes In case of contact with substance, immediately flush with running water for at least 20 minutes.

Transport.
UN number 1361
Response guide 133
Hazard class 4.2
Packing Group II; III