N-Ethyldimethyl amine
- N,N-Dimethylethylamine
- N,N-Dimethylaminoethane
- Methanamine, N-ethyl-N-methyl-
N-Ethyldimethyl amine | |
| |
| Formula | C4H11N |
| Structure | |
| Description | A clear colorless liquid with a strong odor that can vary from ammonia-like to fishlike. |
| Uses | As curing catalyst for resin bonding of sand cores. |
| Registry Numbers and Inventories. | |
| CAS | 598-56-1 |
| EC (EINECS/ELINCS) | 209-940-8 |
| EC Index Number | 612-076-00-8 |
| EC Class | Extremely flammable; Harmful; Corrosive |
| EC Risk Phrase | R 12 20/22 34 |
| EC Safety Phrase | S 3 16 26 36 45 |
| UN (DOT) | 2733 |
| Beilstein/Gmelin | 1696893 |
| Beilstein Reference | 4-04-00-00312 |
| Swiss Giftliste 1 | G-9557 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C4H11N |
| Formula mass | 73.05 |
| Melting point, °C | -140 |
| Boiling point, °C | 36 |
| Vapor pressure, mmHg | 395 (20 C) |
| Vapor density (air=1) | 2.52 |
| Density | 0.675 g/cm3 |
| Solubility in water | Very soluble |
| Refractive index | 1.3705 (25 C) |
| pKa/pKb | 9.83 (pKa) |
| Hazards and Protection. | |
| Storage | Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Flammables-area. |
| Handling | Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid anhydrides. |
| Decomposition | Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | -45.5 | |||
| Autoignition, °C | 190 | |||
| Upper exp. limit, % | 11.2 | |||
| Lower exp. limit, % | 0.9 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. | |||
| Fire potential | Extremely flammable liquid. | |||
| Hazards | Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Containers may explode in the heat of a fire. | |||
| Combustion products | Fire will produce irritating, corrosive and/or toxic gases. | |||
| NFPA | Health | 3 | ||
| Flammability | 4 | |||
| Reactivity | 0 | |||
| Health. | |
| Poison_Class | 2 |
| Exposure effects | |
| Ingestion | May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. |
| Inhalation | Causes chemical burns to the respiratory tract. Vapors may cause dizziness or suffocation. |
| Skin | Causes skin burns. |
| Eyes | Causes eye burns. |
First aid |
|
| Ingestion | Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. |
| Inhalation | Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. |
| Skin | Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. |
| Eyes | Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). |
| Transport. | ||
| UN number | 2733 | |
| Response guide | 132 | |
| Hazard class | 3 | |
| Packing Group | I; II; III | |
| USCG Compatatibility Group | 7. Aliphatic amines | |
| HS Code | 2921 19 80 | |
| Std. Transport # | 4907825 | |