Phenyl glycidyl ether
- 1,2-Epoxy-3-phenoxybenzene
- Phenoxy methyloxirane
- 2,3-Epoxypropyl phenyl ether
Phenyl glycidyl ether | |
| |
| Formula | C9H10O2 |
| Structure | |
| Description | Colorless liquid. Solid below 3.3 Deg c. |
| Uses | Intermediate & stabilizer of halogenated compound. |
| Registry Numbers and Inventories. | |
| CAS | 122-60-1 |
| EC (EINECS/ELINCS) | 204-557-2 |
| EC Index Number | 603-067-00-X |
| EC Class | Carcinogenic Category 2; Mutagenic Category 3; Harmful; Irritant; Sensitising; Dangerous for the Environment |
| EC Risk Phrase | R 45 E20 37/38 43 52/53 68 |
| EC Safety Phrase | S 53 45 61 |
| RTECS | TZ3675000 |
| RTECS class | Tumorigen; Mutagen; Reproductive Effector; Primary Irritant |
| Beilstein/Gmelin | 2744 |
| Beilstein Reference | 5-17-03-00013 |
| Swiss Giftliste 1 | G-2724 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C9H10O2 |
| Formula mass | 150.18 |
| Melting point, °C | 2 - 4 |
| Boiling point, °C | 245 |
| Vapor pressure, mmHg | 0.01 (25 C) |
| Vapor density (air=1) | 5.2 |
| Saturation Concentration | 13.16 ppm (0.0013%) at 20 C (calculated) |
| Critical temperature | 447 |
| Critical pressure | 29.11 |
| Density | 1.1114 g/cm3 |
| Solubility in water | 2.4 g/L |
| Viscosity | 7 MPA 20.00 C |
| Refractive index | 1.5309 |
| Partition coefficient, pKow | 1.12 |
| Heat of fusion | 17.3 kJ/mol |
| Heat of vaporization | 69.85 kJ/mol |
| Heat of combustion | -4801 kJ/mol |
| Hazards and Protection. | |
| Storage | Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. |
| Handling | Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. |
| Disposal code | 1 |
| Stability | Stable under normal temperatures and pressures. |
| Incompatibilities | Oxidizing agents, acids, bases, amines. |
| Decomposition | Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | 114 | |||
| Autoignition, °C | 430 | |||
| Lower exp. limit, % | 1.1 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water fog, dry chemical, carbon dioxide or alcohol type foam. | |||
| Fire potential | This chemical is probably combustible. | |||
| Health. | |
| Exposure limit(s) | OSHA PEL: TWA 10 ppm (60 mg/m3) NIOSH REL: Ca C 1 ppm (6 mg/m3) 15-minute See Appendix A NIOSH IDLH: Potential occupational carcinogen 100 ppm |
| Carcinogin | G-A3, I-2B, CP65 |
| Poison_Class | 4 |
| Exposure effects | Prolonged or repeated skin contact may cause defatting and dermatitis. |
| Ingestion | Ingestion of large amounts may cause gastrointestinal irritation. |
| Inhalation | May cause respiratory tract irritation. |
| Skin | Causes skin irritation. May be harmful if absorbed through the skin. Chronic exposure may result in sensitization. |
| Eyes | Causes eye irritation. |
First aid |
|
| Ingestion | If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. |
| Inhalation | Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. |
| Skin | Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Eyes | Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Transport. | ||
| USCG Compatatibility Group | 41. Ethers | |
| HS Code | 2910 90 00 | |