Tantalum

Formula Ta
Structure
Description Gray metal. Odorless.
Uses In rectifiers, esp for railway signals, in electrolysis capacitors, in manufacture of radio & power tubes.

Registry Numbers and Inventories.
CAS 7440-25-7
EC (EINECS/ELINCS) 231-135-5
RTECS WW5505000
RTECS class Tumorigen
UN (DOT) 3089
Merck 12,9223
Beilstein/Gmelin 16312 (G)
Swiss Giftliste 1 G-4652
Canada DSL/NDSL DSL
US TSCA Listed
Austrailia AICS Listed
New Zealand Listed
Korea ECL Listed

Properties.
Formula Ta
Formula mass 180.94
Melting point, °C 2996
Boiling point, °C 5427
Density 16.69 g/cm3 (20 C)
Solubility in water Insoluble
Thermal expansion 6.55E-06/K
Heat of fusion 33.7 kJ/mol

Hazards and Protection.
Storage Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection Wear appropriate protective gloves, clothing and goggles.
Respirators Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks ELIMINATE all ignition sources. Do not touch or walk through spilled material. Stop leak if you can do it without risk.
Stability Powder ignites SPONTANEOUSLY in air.
Incompatibilities Keep away from strong oxidizers, bromine tri fluoride and fluorine.

Fire.
Fire fighting DO NOT USE WATER, FOAM OR carbon dioxide. Dousing metallic fires with water may generate hydrogen gas, an extremely dangerous explosion hazard, particularly if fire is in a confined environment. Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met-L-X powder. Confining and smothering metal fires is preferable rather than applying water.
Hazards Oxides from metallic fires are a severe health hazard. Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure limit(s) NIOSH REL: TWA 5 mg/m3 ST 10 mg/m3 OSHA PEL: TWA 5 mg/m3 IDLH 2500 mg/m3 (as Ta)
Poison_Class -
Exposure effects
   Ingestion See Inhalation.
   Inhalation Substance or decomposition products may cause severe injury or death.
   Skin See Inhalation.
   Eyes See Inhalation.

First aid
 
   Ingestion The possible benefit of early removal of some ingested material by cautious gastric lavage must be weighed against potential complications of bleeding or perforation. Activated charcoal activated charcoal binds most toxic agents and can decrease their systemic absorption if administered soon after ingestion. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.
   Inhalation Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
   Skin Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes.
   Eyes Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Transport.
UN number 3089
Response guide 170
Hazard class 4.1
Packing Group II; III