Turpentine

  • Oil of turpentine
  • Spirit of turpentine
  • Turps
  • Turpentine oil
  • Gum turpentine
  • Wood turpentine
Formula Mixture
Description A clear colorless liquid with a characteristic odor.
Uses Paint thinner, making of vanishes and treatment of lice.

Registry Numbers and Inventories.
CAS 8006-64-2
EC (EINECS/ELINCS) 232-350-7
EC Index Number 650-002-00-6
EC Class Flammable; Harmful; Irritant; Sensitizing; Dangerous for the Environment
EC Risk Phrase R 10 20/21/22 36/38 43 51/53 65
EC Safety Phrase S 36/37 46 61 62
RTECS YO8400000
RTECS class Tumorigen; Human Data; Primary Irritant
UN (DOT) 1299
Beilstein/Gmelin NA
EPA OPP 84501
Swiss Giftliste 1 G-2910
Canada DSL/NDSL DSL
US TSCA Listed
Austrailia AICS Listed
New Zealand Listed
Korea ECL Listed

Properties.
Melting point, °C -60
Boiling point, °C 154
Vapor pressure, mmHg 577 (25 C)
Vapor density (air=1) 4.7
Evaporization number 0.86 (butyl acetate=1)
Solubility in water Insoluble

Hazards and Protection.
Storage Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
WHMIS B2 D2B
Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. All five-gallon pails and larger metal containers, including tank cars and tank trucks, should be grounded and/or bonded when material is transferred.
Protection Wear appropriate protective gloves, clothing and goggles.
Respirators Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors.
Stability Stable at normal temperatures and pressures.
Incompatibilities Calcium hypochlorite, chlorine, chromic anhydride, chromyl chloride, hexachloromelamine, stannic chloride, and trichloromelamine.
Decomposition Carbon dioxide and carbon monoxide, nitrogen compounds, various hydrocarbons.

Fire.
Flash Point,°C 35
Autoignition, °C 253
Lower exp. limit, % 0.8
Fire fighting Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may spread fire. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide.
Fire potential HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards Forms heavy black smoke and soot
Combustion products Fire may produce irritating, corrosive and/or toxic gases.
NFPA Health 1
  Flammability 3  
  Reactivity 0  

Health.
Exposure limit(s) OSHA PEL: 560mg/M3, ACGIH TLV: 556 mg/M3
Exposure effects
   Ingestion Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal.
   Inhalation May cause respiratory tract irritation. Aspiration may cause respiratory swelling and pneumonitis.
   Skin Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
   Eyes Contact with eyes may cause severe irritation, and possible eye burns.

First aid
 
   Ingestion Seek medical assistance.
   Inhalation Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes
   Eyes Flush with running water for at least 20 minutes.

Transport.
UN number 1299
Response guide 128
Hazard class 3
Packing Group III  
USCG CHRIS Code TPT  
USCG Compatatibility Group 30 Olefins
Std. Transport # 4912414 4910313 4910326  
IMO Pollution Category B
IMO Hazard code P