o-sec-Butylphenol
- 2-sec-Butylphenol
- 2-(1-Methylpropyl)phenol
o-sec-Butylphenol | |
| |
| Formula | C10H14O |
| Structure | |
| Description | Clear colorless liquid. |
| Uses | Chemical intermediate in prepn of resins, plasticizers, surface active agents & other products. |
| Registry Numbers and Inventories. | |
| CAS | 89-72-5 |
| EC (EINECS/ELINCS) | 201-933-8 |
| EC Risk Phrase | R 21/22 34 |
| EC Safety Phrase | S 26 36/37/39 45 |
| RTECS | SJ8920000 |
| RTECS class | Primary Irritant |
| UN (DOT) | 2228 |
| Beilstein/Gmelin | 1210026 |
| Beilstein Reference | 3-06-00-01852 |
| Swiss Giftliste 1 | G-8136 |
| Canada DSL/NDSL | DSL |
| US TSCA | Listed |
| Austrailia AICS | Listed |
| New Zealand | Listed |
| Japan ENCS (MITI) | Listed |
| Korea ECL | Listed |
| Properties. | |
| Formula | C10H14O |
| Formula mass | 150.24 |
| Melting point, °C | 12.2 |
| Boiling point, °C | 227 |
| Density | 0.9981 g/cm3 (20 C) |
| Solubility in water | Insoluble |
| Refractive index | 1.5228 (20 C) |
| Partition coefficient, pKow | 3.27 |
| Hazards and Protection. | |
| Storage | Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. |
| Handling | Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood. Wash clothing before reuse. |
| Protection | Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. |
| Respirators | Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. |
| Small spills/leaks | Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. |
| Stability | Stable at room temperature in closed containers under normal storage and handling conditions. |
| Incompatibilities | Acid anhydrides, acid chlorides, brass, oxidizing agents, steel, bases, copper, copper alloys. |
| Decomposition | Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
| Fire. | ||||
| Flash Point,°C | 107.2 | |||
| Fire fighting | Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Combustible material; may burn but does not ignite readily. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. | |||
| Fire potential | This chemical is combustible. | |||
| Hazards | When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |||
| Combustion products | Fire may produce irritating, corrosive and/or toxic gases. | |||
| NFPA | Health | 2 | ||
| Flammability | 1 | |||
| Reactivity | 0 | |||
| Health. | |
| Exposure limit(s) | NIOSH REL: TWA 5 ppm (30 mg/m3) [skin] |
| Poison_Class | 4 |
| Exposure effects | May cause liver and kidney damage. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed. |
| Ingestion | Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause burns to the digestive tract. May cause central nervous system effects. |
| Inhalation | Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause liver and kidney damage. May cause adverse central nervous system effects including headache, convulsions, and possible death. May cause burns to the respiratory tract. May cause cardiac abnormalities. Can produce delayed pulmonary edema. |
| Skin | Causes severe skin irritation and possible burns. |
| Eyes | Causes severe eye irritation and possible burns. May cause chemical conjunctivitis. |
First aid |
|
| Ingestion | Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. |
| Inhalation | Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. |
| Skin | Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. |
| Eyes | Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
| Transport. | ||
| UN number | 2228 | |
| Response guide | 153 | |
| Hazard class | 6.1 | |
| Packing Group | III | |
| USCG Compatatibility Group | 21. Phenols. Cresols | |